To see where the SSP project thinks your license file is located you can create a Synergy project and check the configuration window. You will see something similar to the image below. The License File pull-down will list the location for the license file. If no location is listed, you will need to use the browse button (...) to set the license location. Once it is set correctly you can also view the license details to make sure you have the features you expect.
You can also find this screen under Window >> Preferences, then go to C/C++ >> Renesas >> Synergy >> Synergy License (or just put in Synergy in the search box).
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